Organoelement Compounds
Full Access
ChemInform Abstract: Hydride Transfer Reactions Between Penta- and Tetracoordinate Silicon Derivatives.
First published: January 26, 1993
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract
Studies show that KHSi(O-R)4 (R: -Et, -iPr) reduces Ph3SiF and Ph3SiCl and induces H/D exchange with Ph3SiD and Ph2SiD2. This easy and fast transfer seems to occur by a one-step concerted mechanism via a binuclear intermediate with bridging H and D atoms.
