Volume 24, Issue 4
Heterocyclic Compounds
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ChemInform Abstract: Alternative Approach to 2,6-Diaryl-3,7-dioxabicyclo(3.3.0)octane Lignans Using an Alicyclic Claisen Rearrangement.

H. M. BRADLEY

H. M. BRADLEY

Chem. Dep., Univ. Park, Nottingham NG7 2RD, UK

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R. G. JONES

R. G. JONES

Chem. Dep., Univ. Park, Nottingham NG7 2RD, UK

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D. W. KNIGHT

D. W. KNIGHT

Chem. Dep., Univ. Park, Nottingham NG7 2RD, UK

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First published: January 26, 1993

Abstract

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ChemInform Abstract

The title compound (IX) is synthesized as outlined in the reaction scheme. Key step is the enolate Claisen rearrangement of the macrolide (VI).

chemical structure image

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