Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of (C5H5)Fe(CO)(SiHPh2)2H, a Catalytically Active Intermediate in the Hydrosilylation of Acetophenone by Diphenylsilane.
First published: October 1, 1991
Abstract
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ChemInform Abstract
During the hydrosilylation of acetophenone (I) with the well-known complex (IV) as the catalyst the new title complex (V) is formed as an intermediate. On reaction of (IV) with an excess of (II) in the absence of (I), (V) can be isolated and is characterized by IR and 1H NMR spectra. (V) is much more effective catalyst than its precursor ( IV).
