ChemInform Abstract: Formation of Acetylplatina(IV)cyclobutane: Methodology for the Synthesis of Platina(IV)cyclobutane Complexes Bearing Electrophilic Substituents.
Abstract
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ChemInform Abstract
Hydrolysis of the platina-cyclobutane complex (IV) gives a mixture of ( V) and the isomer (VI). This apparent isomerization can be prevented when the bidentate ligand bipyridine (VII) is used instead of (III) affording a single isomer (VIII).