Volume 22, Issue 16
Physical Organic Chemistry
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ChemInform Abstract: (Z)-2,2,5,5-Tetramethyl-3,4-diphenyl-3-hexene: A Cofacial Stilbene.

J. E. GANO

J. E. GANO

Dep. Chem., Univ. Toledo, Toledo, OH 43606, USA

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B.-S. PARK

B.-S. PARK

Dep. Chem., Univ. Toledo, Toledo, OH 43606, USA

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A. A. PINKERTON

A. A. PINKERTON

Dep. Chem., Univ. Toledo, Toledo, OH 43606, USA

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D. LENOIR

D. LENOIR

Dep. Chem., Univ. Toledo, Toledo, OH 43606, USA

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First published: April 23, 1991

Abstract

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ChemInform Abstract

Unexpectedly, the strain introduced by the vicinal tert.-butyl groups of the title compound (I) is not relieved by twisting of the double bond. As shown by single crystal X-ray analysis the phenyl rings are forced together in a cofacial or face-to-face relationship.

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