Volume 21, Issue 37
Heterocyclic Compounds
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ChemInform Abstract: Addition of N-Methylnitrone to 1-Bromo-1-perfluoroalkylethene. A Two Step 1,3-Dipolar Cycloaddition Reaction.

J. FAYN

J. FAYN

Lab. Chim. Org. Fluor, Univ., 06034 Nice, France

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A. CHAMBON

A. CHAMBON

Lab. Chim. Org. Fluor, Univ., 06034 Nice, France

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First published: September 11, 1990

Abstract

Reaction of the 1-bromo-1-perfluoroalkylethenes (I) with in situ generated N-methylnitrone in an alcoholic solution gives the 5-alkoxy-2-methyl-5-perfluoroalkylisoxazolidines (IV).

ChemInform Abstract

Reaction of the 1-bromo-1-perfluoroalkylethenes (I) with in situ generated N-methylnitrone in an alcoholic solution gives the 5-alkoxy-2-methyl-5-perfluoroalkylisoxazolidines (IV). A two step mechanism is proposed.

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