ChemInform Abstract: Metal Ion Induced Rearrangements of 1,3,4-Thiadiazolidine-2-thiones. Part 1. The Rearrangements of 3-Methyl-5-(2-pyridyl)- and 3-Methyl-5-(6-methylpyrid-2-yl)-1,3,4-thiadiazolidine-2-thiones with Nickel(II), Zinc(II) and Cadmium(II) Ions.
Abstract
The thiadiazolidine-2-thiones (I) react with nickel(II), zinc(II) and cadmium(II) acetates to produce intensely colored, stable complexes.
ChemInform Abstract
The thiadiazolidine-2-thiones (I) react with nickel(II), zinc(II) and cadmium(II) acetates to produce intensely colored, stable complexes. Conductance, magnetic and spectroscopic evidences indicate that the rearrangement of (I) to the corresponding Schiff bases occurs.