Organoelement Compounds
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ChemInform Abstract: Synthesis and Characterization of the Organozirconium and Organohafnium Complexes ((η5-C5Me5)MCl)3O(OH)3Cl and ((η5-C5Me5)MCl)3O(OH)4.
First published: May 30, 1989
Abstract
The title complexes (III) and (IV) are synthesized by base-catalyzed hydrolysis depending on the stoichiometry.
ChemInform Abstract
The title complexes (III) and (IV) are synthesized by base-catalyzed hydrolysis depending on the stoichiometry. Conversion of the chloride-bridged compounds (III) into the μ3-OH analogues (IV) proceeds in greater than 65% yield. The structure of the Zr compound (IVa), directly synthesized from (Ia) and 2 equiv. H2O in the presence of 2 equiv. NEt3 in 65% yield, is determined by X-ray analysis (space group Pbca, Z = 8).
