ChemInform Abstract: Pseudochalcogen Compounds. Part 18. Cyanamidolysis of Organophosphoryl-(phosphonyl-)chlorides.
Abstract
Cyanamidolytic reactions of organophosphoryl and -phosphonyl chlorides are leading in dependence on the reaction conditions to metal organocyanamidophosphates e.g. (I) and -cyanamidophosphonates e.g. (II), respectively, and by-products such as (III), as well as to corresponding organophosphoryl-hydrogencyanamides e.g. (IV) and to bis(organylphosphoryl)- and bis(organophosphonyl)carbodiimides such as (V) and (VI).
ChemInform Abstract
Cyanamidolytic reactions of organophosphoryl and -phosphonyl chlorides are leading in dependence on the reaction conditions to metal organocyanamidophosphates e.g. (I) and -cyanamidophosphonates e.g. (II), respectively, and by-products such as (III), as well as to corresponding organophosphoryl-hydrogencyanamides e.g. (IV) and to bis(organylphosphoryl)- and bis(organophosphonyl)carbodiimides such as (V) and (VI). Some Ag(I) and Pd(II) analogues to (I), (II), and (III) are also prepared. Conditions for synthesis as well as properties and structures of the new compounds are discussed on the basis of characteristic IR and 31P NMR data.
