Preparative Organic Chemistry
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ChemInform Abstract: Aminated Polystyrene-Bound Carbonylrhodium Clusters as a Catalyst for Deoxygenation of Various N-O Bonds.
First published: May 30, 1989
Abstract
Poly(p-chloromethylstyrene) is partially aminated to yield ligands which form polymer-bound carbonylrhodium amine complexes.
ChemInform Abstract
Poly(p-chloromethylstyrene) is partially aminated to yield ligands which form polymer-bound carbonylrhodium amine complexes. These are employed as catalysts in the deoxygenation of 1-nitropropane (I) or N,N-diethylhydroxylamine (VII) with CO/H2O, producing mainly propionitrile (III) and diethylamine (VIII) respectively.
