Preparative Organic Chemistry
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ChemInform Abstract: The NEER Principle. Ground-State Conformational Bias in Triene Photocyclizations.
First published: May 30, 1989
Abstract
The diastereoselectivity observed for the photocyclization of the six trienes (I) and (IV) can be rationalized as the result of conformational bias in the ground states of the starting trienes.
ChemInform Abstract
The diastereoselectivity observed for the photocyclization of the six trienes (I) and (IV) can be rationalized as the result of conformational bias in the ground states of the starting trienes. The results (no details given) thereby lend experimental support to the Non-Equilibration of Excited Rotamers or NEER principle.
