Preparative Organic Chemistry
Full Access
ChemInform Abstract: Geminal Systems. Part 40. Rearrangement of the Cyclopropyl - Allyl Type During the Thermolysis of Bicyclic N-Haloaziridines.
First published: May 30, 1989
Abstract
Thermolysis of the N-halodiazabicyclohexanecarboxylates (I) gives the haloacrylates (II).
ChemInform Abstract
Thermolysis of the N-halodiazabicyclohexanecarboxylates (I) gives the haloacrylates (II). The reaction does not proceed via the corresponding α-azo-δ-halopentanoates as proven by the thermolysis of the δ-chloro compound (IV). (Kinetics, mechanism).
