Preparative Inorganic Chemistry
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ChemInform Abstract: Contributions to the Chemistry of Phosphorus. Part 191. Reaction Behavior of Sodium Tetraphosphinoborate NaB(PH2)4.
First published: May 30, 1989
Abstract
The title compound (I) rearranges to the heptaphosphinodiborate (II) in THF at moderate temperatures.
ChemInform Abstract
The title compound (I) rearranges to the heptaphosphinodiborate (II) in THF at moderate temperatures. Reactions with the Lewis acid BH3 yields (IV) and methylation affords (VI). The 31P and 11B NMR spectra of (II), (IV), and (VI) are reported and discussed.
