Physical Inorganic Chemistry
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ChemInform Abstract: Reaction of Hydrogen Peroxide with Metal Complexes. Part 10. Formation Kinetics of Peroxovanadium(V) Complexes in Strongly Acidic Media as Studied by a High-Pressure Stopped-Flow Technique.
First published: May 30, 1989
Abstract
The kinetics of the reactions outlined in the scheme are studied under pseudo-first-order conditions (i.e., > 20fold excess of H2O2) at various temp. and pressures.
ChemInform Abstract
The kinetics of the reactions outlined in the scheme are studied under pseudo-first-order conditions (i.e., > 20fold excess of H2O2) at various temp. and pressures. Rate equations and activation parameters are reported. Positive volumes of activation observed for the formation of the monoperoxo-complex are attributed to a transition state with distorted pentagonal-bipyramidal structure.
