Volume 20, Issue 22
Physical Inorganic Chemistry
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ChemInform Abstract: A Pulse Radiolysis Based Singlet Oxygen Luminescence Facility.

A. A. GORMAN

A. A. GORMAN

Dep. Chem., Univ. Manchester, Manchester M13 9PL, UK

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I. HAMBLETT

I. HAMBLETT

Dep. Chem., Univ. Manchester, Manchester M13 9PL, UK

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E. J. LAND

E. J. LAND

Dep. Chem., Univ. Manchester, Manchester M13 9PL, UK

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First published: May 30, 1989

Abstract

The first successful time-resolved detection of O2(1Δg) luminescence is achieved by using the pulse radiolysis technique.

ChemInform Abstract

The first successful time-resolved detection of O2(1Δg) luminescence is achieved by using the pulse radiolysis technique. The use of a germanium detector, which is highly sensitive in the IR region, and a fast, low noise, high gain amplifier greatly enhances the accuracy of the determinations of luminescence yield, lifetime, and decay rate. The detection configuration is briefly described.

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