Organoelement Compounds
Full Access
ChemInform Abstract: (Mn10O14(N(CH2CH2NH2)3)6)8+: A Mixed-Valence Polyoxomanganese Polycation Possessing Structural Similarities to Naturally Occurring Layered Manganese Oxides.
First published: May 2, 1989
Abstract
The title complex (I) is obtained by dissolving Mn(O-SO2-CF3)2·2 MeCN and the ligand in acetonitrile under N2 and overnight exposure to air.
ChemInform Abstract
The title complex (I) is obtained by dissolving Mn(O-SO2-CF3)2·2 MeCN and the ligand in acetonitrile under N2 and overnight exposure to air. The structure of the compound is determined by an X-ray analysis (space group P1, Z=1). The cation consists of four Mn(III) and six Mn(IV) atoms. (I) represents the first example of a structurally defined high-nuclearity non-carboxylate manganese-oxo complex.
