ChemInform Abstract: Halogen, Hydride, and Alkyl Carbonyl-Monocyclopentadienyl Niobium Derivatives. Crystal and Molecular Structure of (Nb(η-C5H5)Cl(H)(CO)(PMe3)2).
Abstract
The reduction of the complexes (I) with sodium amalgam yields the products (II) which serve as starting materials for new halogen, hydride, and alkyl Nb(I)- and Nb(III) derivatives.
ChemInform Abstract
The reduction of the complexes (I) with sodium amalgam yields the products (II) which serve as starting materials for new halogen, hydride, and alkyl Nb(I)- and Nb(III) derivatives. For the title hydride complex (IIIa) the X-ray crystal structure is determined (space group P21/a, Z=4).