Volume 20, Issue 18
Organoelement Compounds
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ChemInform Abstract: Halogen, Hydride, and Alkyl Carbonyl-Monocyclopentadienyl Niobium Derivatives. Crystal and Molecular Structure of (Nb(η-C5H5)Cl(H)(CO)(PMe3)2).

F. A. JALON

F. A. JALON

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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A. OTERO

A. OTERO

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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P. ROYO

P. ROYO

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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J. L. BALCAZAR

J. L. BALCAZAR

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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F. FLORENCIO

F. FLORENCIO

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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S. GARCIA-BLANCO

S. GARCIA-BLANCO

Dep. Quim. Inorg., Univ. Alcala de Henares, Alcala de Henares, Spain

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First published: May 2, 1989

Abstract

The reduction of the complexes (I) with sodium amalgam yields the products (II) which serve as starting materials for new halogen, hydride, and alkyl Nb(I)- and Nb(III) derivatives.

ChemInform Abstract

The reduction of the complexes (I) with sodium amalgam yields the products (II) which serve as starting materials for new halogen, hydride, and alkyl Nb(I)- and Nb(III) derivatives. For the title hydride complex (IIIa) the X-ray crystal structure is determined (space group P21/a, Z=4).

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