Preparative Organic Chemistry
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ChemInform Abstract: Protodesilylation of Allylsilanes for the Control of Double Bond Geometry Exocyclic to a Ring.
First published: May 2, 1989
Abstract
The protodesilylation of the allylic silanes (I) or (IV) is selective for the formation of the geometrical isomers (II) and (III) when the group R is isopropyl, but not when it is methyl.
ChemInform Abstract
The protodesilylation of the allylic silanes (I) or (IV) is selective for the formation of the geometrical isomers (II) and (III) when the group R is isopropyl, but not when it is methyl. - The substrate (Ia) is obtained from the acetate (V) (no experimental details given).
