Volume 20, Issue 2
Organoelement Compounds
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ChemInform Abstract: Easy One-Step General Synthesis of Acylsilanes.

A. CAPPERUCCI

A. CAPPERUCCI

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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A. DEGL'INNOCENTI

A. DEGL'INNOCENTI

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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C. FAGGI

C. FAGGI

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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A. RICCI

A. RICCI

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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P. DEMBECH

P. DEMBECH

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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G. SECONI

G. SECONI

Centro CNR Chim. Strut. Comp. Eterocic. Appl., Dip. Chim. Org., Univ., 50121 Firence, Italy

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First published: January 10, 1989

Abstract

The acyl chlorides (I), as well as the diacid dichlorides (IV) and (VI) react with (trimethylsilyl)cuprate, generated in situ from (trimethylsilyl)lithium (II) and CuCN, to give the acylsilanes (III), (V), and (VII).

ChemInform Abstract

The acyl chlorides (I), as well as the diacid dichlorides (IV) and (VI) react with (trimethylsilyl)cuprate, generated in situ from (trimethylsilyl)lithium (II) and CuCN, to give the acylsilanes (III), (V), and (VII). The compound (IX) is obtained from the acid chloride (VIII) using the same method.

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