ChemInform Abstract: Easy One-Step General Synthesis of Acylsilanes.
Abstract
The acyl chlorides (I), as well as the diacid dichlorides (IV) and (VI) react with (trimethylsilyl)cuprate, generated in situ from (trimethylsilyl)lithium (II) and CuCN, to give the acylsilanes (III), (V), and (VII).
ChemInform Abstract
The acyl chlorides (I), as well as the diacid dichlorides (IV) and (VI) react with (trimethylsilyl)cuprate, generated in situ from (trimethylsilyl)lithium (II) and CuCN, to give the acylsilanes (III), (V), and (VII). The compound (IX) is obtained from the acid chloride (VIII) using the same method.