Physical Inorganic Chemistry
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ChemInform Abstract: Potential Oscillations During the Electrocrystallization of Cadmium from Alkaline Cyanide Solutions Under Galvanostatic Conditions.
First published: January 10, 1989
Abstract
During electrolysis under galvanostatic conditions carried out at current densities which are above the limiting current (caused by the diffusion control of the Cd complex ion with natural convection) potential oscillations are observed and H2 bubbles are evolved periodically from the cathode surface.
ChemInform Abstract
During electrolysis under galvanostatic conditions carried out at current densities which are above the limiting current (caused by the diffusion control of the Cd complex ion with natural convection) potential oscillations are observed and H2 bubbles are evolved periodically from the cathode surface. The detailed mechanism explaining these phenomena is given.
