Organoelement Compounds
Full Access
ChemInform Abstract: Protonation of Transition-Metal Acetate and Hydrido Acetate Complexes with Fluorocarbon Acids.
First published: August 16, 1988
Abstract
The reactions of (IV) with the fluorocarbon acid (II) yield the cationic, binuclear compound (V).
ChemInform Abstract
The reactions of (IV) with the fluorocarbon acid (II) yield the cationic, binuclear compound (V). Reaction of (VIa) with (II) at 20 °C gives the π-arene complex (X), whereas the Os analogue (VIb) provides (VII) (P1, Z=2) in which a molecular hydrogen ligand has been characterized by its 1H spin-lattice relaxation time. Elimination of acetic acid and formation of (IX) occurs on reaction with acetonitrile.
