Volume 19, Issue 4
Organoelement Compounds
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ChemInform Abstract: Generation of Re2(CO)9(N2) from Re2(CO)10: Identification of Photochemical Intermediates by Matrix Isolation and Liquid-Noble-Gas Techniques.

S. FIRTH

S. FIRTH

MPI Strahlenchem., D-4330 Muelheim/R.

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W. E. + KLOTZBUECHER

W. E. + KLOTZBUECHER

MPI Strahlenchem., D-4330 Muelheim/R.

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M. POLIAKOFF

M. POLIAKOFF

MPI Strahlenchem., D-4330 Muelheim/R.

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J. J. TURNER

J. J. TURNER

MPI Strahlenchem., D-4330 Muelheim/R.

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First published: January 26, 1988

Abstract

UV photolysis of Re2(CO)10 in liquid xenon doped with N2 or in an N2 matrix at 20 K generates eq-Re2(CO)9(N2).

ChemInform Abstract

UV photolysis of Re2(CO)10 in liquid xenon doped with N2 or in an N2 matrix at 20 K generates eq-Re2(CO)9(N2). Similar results are found for Mn2(CO)10 and MnRe(CO)10.

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