Volume 18, Issue 38
Organic Dyes
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ChemInform Abstract: Structure of “Dioneheme”. Total Synthesis of the Green Heme Prosthetic Group in Cytochrome cd1 Dissimilatory Nitrite Reductase.

W. WU

W. WU

Dep. Chem., Mich. State Univ., East Lansing, MI 48824, USA

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C. K. CHANG

C. K. CHANG

Dep. Chem., Mich. State Univ., East Lansing, MI 48824, USA

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First published: September 22, 1987

Abstract

In order to investigate the structure of heme d1, a green substrate-binding heme prosthetic group of cytochrome cd1, the metal-free "dioneheme" tetramethyl ester (IV) is synthesized starting from the dialdehyde (I).

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