Preparative Organic Chemistry
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ChemInform Abstract: Absolute Stereochemical Control in Allylic Oxidation via Ene Reactions of N-Sulfinylcarbamates.
First published: September 22, 1987
Abstract
Reaction of the title carbamate (I) with the alkenes (II), (IV), (V) and (X) leads to asymmetric induction at sulfur and carbon and the products (III), (VI) (no yields given) and (XI) are formed.
ChemInform Abstract
Reaction of the title carbamate (I) with the alkenes (II), (IV), (V) and (X) leads to asymmetric induction at sulfur and carbon and the products (III), (VI) (no yields given) and (XI) are formed. (VI) and (XI) are transformed to the allylic alcohols (IX) and (XII) with 91 and 100% e.e., respectively.
