Organoelement Compounds
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ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 57. Reactions of Iron-Molybdenum Complexes with Oxygen and Sulfur; Crystal Structure of (FeMo(.mu±eta.2-SCC6H4Me-4)(CO)5(η-C5H5)).
First published: September 1, 1987
Abstract
The preparation of the oxo-bridged species (IIa) occurs stoichiometrically and proceeds in high yield.
ChemInform Abstract
The preparation of the oxo-bridged species (IIa) occurs stoichiometrically and proceeds in high yield. This is in contrast to the preparation of the analogous W compound. The reaction of (I) with sulfur yields a mixture of (IIb) and (III) which is characterized by an X-ray diffraction study (space group P1, Z=2). When the complex (V) is heated in toluene at 60 °C for 2 h it is quantitatively converted to (VI) with loss of CO.
