ChemInform Abstract: Homolytic Alkoxycarbonylation Reactions in Two-Phase Systems. Part 3. Introduction of a Single Carboxylic Acid Ester Function into Cyano- or Alkoxycarbonyl Substituted N-Heteroaromatics.
Abstract
Alkoxycarbonylation of the pyridines (I), (IV), (VI), and the pyridazine (X) with the alkyl pyruvates (II) yields the corresponding esters as shown in the reaction scheme.
ChemInform Abstract
Alkoxycarbonylation of the pyridines (I), (IV), (VI), and the pyridazine (X) with the alkyl pyruvates (II) yields the corresponding esters as shown in the reaction scheme. Polysubstituted by-products are obtained from (IV) (R1: -CN) and (VI).