Physical Inorganic Chemistry
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ChemInform Abstract: Rate Constants for H + O2 + M at 298 K for M: He, N2, and H2O
First published: June 16, 1987
Abstract
have been measured by the discharge-flow technique to be 2.6·10-32, 6.1·10-32, and 6.4·10-31 cm6s-1 respectively.
ChemInform Abstract
have been measured by the discharge-flow technique to be 2.6·10-32, 6.1·10-32, and 6.4·10-31 cm6s-1 respectively. Although the rates for He and N2 can be rationalized in terms of existing theory, that for H2O implies a collision efficiency greater than 1. This can be rectified by use of the total quantum mechanical cross section instead of the Lennard-Jones cross section.
