Physical Organic Chemistry
Full Access
ChemInform Abstract: Nitrous Oxide in Gas-Phase Ion-Molecule Chemistry: A Versatile Reagent for the Determination of Carbanion Structure.
First published: October 7, 1986
Abstract
The reactions of N2O with various anions in the gas phase are highly characteristic of the ion′s structure.
ChemInform Abstract
The reactions of N2O with various anions in the gas phase are highly characteristic of the ion′s structure. In general, prim. carbanions produce diazo anions, sec. carbanions dehydrogenate and tert. carbanions afford adducts, oxygen atom transfer and cleavage products.
