Perfluoro(butylcyclohexane)–Cis-Perfluorodecalin Mixture Separation by Heteroazeotropic Distillation
Corresponding Author
Dr. Egor V. Lupachev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
E-mail: [email protected]
Search for more papers by this authorAlexey V. Kisel
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorSergey. Ya. Kvashnin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorDr. Viktor I. Privalov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Chemistry of Coordination Polynuclear Compounds, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorTatiana D. Ksenofontova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, The Research Equipment Sharing Center of Physical Methods for Studying Substances and Materials, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorDr. Andrei V. Polkovnichenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorCorresponding Author
Dr. Egor V. Lupachev
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
E-mail: [email protected]
Search for more papers by this authorAlexey V. Kisel
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorSergey. Ya. Kvashnin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorDr. Viktor I. Privalov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Chemistry of Coordination Polynuclear Compounds, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorTatiana D. Ksenofontova
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, The Research Equipment Sharing Center of Physical Methods for Studying Substances and Materials, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorDr. Andrei V. Polkovnichenko
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Laboratory of Theoretical Foundations of Chemical Technology, Leninsky prosp., 31, Moscow, 119071 Russia
Search for more papers by this authorAbstract
This work investigates the process of distillation purification of perfluoro(butylcyclohexane) (BCH) and concentration of perfluorodecalin (PFD) from industrial samples of BCH–PFD mixtures. According to experimental data, the main difficulty is the separation of BCH from the cis-isomer of PFD, for which distillation is ineffective. To intensify this process, a heteroazeotropic distillation method in the presence of water was proposed and implemented on a pilot-scale distillation column. This approach allows BCH to be purified from PFD up to more than 0.99 mol.fr. The advantage of the proposed method is the use of a safe separating agent—water, which is especially important due to the widespread use of BCH and PFD in medicine. Based on experimental data, the work also determined the characteristics of heteroazeotropes in the systems BCH–water, cis-PFD–water, and trans-PFD–water and relative volatility between BCH and cis-PFD in the presence of water.
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