Branched Polyvinyl Alcohol Hybrid Membrane for Acid Recovery via Diffusion Dialysis
Corresponding Author
Congliang Cheng
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, 111 Jiulong Road, 230601 Hefei, China
Correspondence: Congliang Cheng ([email protected]), Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, Hefei 230022, Anhui Province, China.Search for more papers by this authorPing Li
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Search for more papers by this authorYubin He
University of Science and Technology of China, CAS Key Laboratory of Soft Matter Chemistry, Laboratory of Functional Membranes, School of Chemistry and Material Science, 96 Jinzhai Road, 230026 Hefei, China
Search for more papers by this authorXianhai Hu
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Search for more papers by this authorKamana Emmanuel
University of Science and Technology of China, CAS Key Laboratory of Soft Matter Chemistry, Laboratory of Functional Membranes, School of Chemistry and Material Science, 96 Jinzhai Road, 230026 Hefei, China
Search for more papers by this authorCorresponding Author
Congliang Cheng
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Anhui Province Key Laboratory of Environment-Friendly Polymer Materials, 111 Jiulong Road, 230601 Hefei, China
Correspondence: Congliang Cheng ([email protected]), Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, Hefei 230022, Anhui Province, China.Search for more papers by this authorPing Li
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Search for more papers by this authorYubin He
University of Science and Technology of China, CAS Key Laboratory of Soft Matter Chemistry, Laboratory of Functional Membranes, School of Chemistry and Material Science, 96 Jinzhai Road, 230026 Hefei, China
Search for more papers by this authorXianhai Hu
Anhui Jianzhu University, School of Material and Chemical Engineering, 856 Jinzhai Road, 230022 Hefei, China
Search for more papers by this authorKamana Emmanuel
University of Science and Technology of China, CAS Key Laboratory of Soft Matter Chemistry, Laboratory of Functional Membranes, School of Chemistry and Material Science, 96 Jinzhai Road, 230026 Hefei, China
Search for more papers by this authorAbstract
A branched polymer was prepared by grafting allyltrimethylammonium chloride onto polyvinyl alcohol (PVA) via free-radical polymerization. Afterwards, a series of hybrid membranes were prepared by sol-gel cross-linking between quaternary ammonium-PVA and tetraethoxysilane. The obtained membranes were characterized in terms of infrared spectroscopy, ion exchange capacity, water uptake, linear expansion ratio, and acid resistance. The thermal properties of the membranes were investigated as well. The diffusion dialysis performances of the membranes were tested by using a simulated feed solution containing HCl and FeCl2. The diffusion dialysis coefficients and the separation factors were much better than those of the commercial DF-120 membrane.
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