Article
Full Access
CO2 Laser-Induced Photodesorption of Physisorbed Ammonia from Cu(100) Single Crystal
Ingo Hussla,
T. J. Chuang,
Ingo Hussla
IBM Research Laboratory, San Jose, California 95193, U.S.A.
Search for more papers by this authorT. J. Chuang
IBM Research Laboratory, San Jose, California 95193, U.S.A.
Search for more papers by this authorIngo Hussla,
T. J. Chuang,
Ingo Hussla
IBM Research Laboratory, San Jose, California 95193, U.S.A.
Search for more papers by this authorT. J. Chuang
IBM Research Laboratory, San Jose, California 95193, U.S.A.
Search for more papers by this authorAbstract
Infrared laser-induced photodesorption of physisorbed NH3 from Cu(100) single crystal is achieved via resonant pulsed CO2 laser excitation of the symmetric deformation mode δ3 and-detected by time-of-flight mass spectrometry. Photofragmentation and photoionization at increased laser intensities are also observed.
Reference
- 1 J. Heidberg, H. Stein, A. Nestmann, E. Hoefs, and I. Hussla, Symposium “Laser-Solid Interactions and Laser Processing”, 1978, Boston, Massachusetts, USA, Materials Research Society Proceedings, eds. S. D. Ferris, H. J. Leamy, and J. M. Poate (American Institute of Physics, New York 1979), p. 49.
- 2 J. Heidberg, H. Stein, E. Riehl, and A. Nestmann, Z. Phys. Chem. N.F. 121, 145 (1980).
- 3
J. Heidberg,
H. Stein, and
E. Riehl,
in: “Vibrations at Surfaces”,
eds. R. Caudano,
J. M. Gilles, and
A. A. Lucas
(Plenum Press, New York
1982),
p. 17.
10.1007/978-1-4684-4058-4_2 Google Scholar
- 4 J. Heidberg, H. Stein, and E. Riehl, Phys. Rev. Lett. 49, 666 (1982).
- 5 J. Heidberg, H. Stein, and E. Riehl, Surf. Sci. 126, 183 (1983).
- 6
J. Heidberg,
H. Stein,
E. Riehl, and
I. Hussla,
in: “Surface Studies with Lasers”,
eds. F. R. Aussenegg,
A. Leitner, and
M. E. Lippitsch
(Springer Verlag, Berlin
1983),
p. 226.
10.1007/978-3-642-82085-4_37 Google Scholar
- 7 J. Heidberg, “Symposium Laser Controlled Chemical Processing of Surfaces”, 1983, Boston, Massachusetts, U.S.A., Materials Research Society Proceedings, eds. A. Wayne Johnson and D. J. Ehrlich (North Holland 1984), p. 333.
- 9 J. Heidberg and I. Hussla, J. Electron. Spectrosc. Relat. Phenom. 29, 105 (1983).
- 10 J. Heidberg and I. Hussla, Appl. Phys. B29, 184 (1983).
- 11 T. J. Chuang and F. A. Houle, J. Vac. Sci. Technol. 20, 603 (1982).
- 12 T. J. Chuang, J. Chem. Phys. 76, 3828 (1982).
- 13 T. J. Chuang, J. Electron. Spectrosc. Relat. Phenom. 29, 125 (1983).
- 14 T. J. Chuang and H. Seki, Phys. Rev. Lett. 49, 382 (1982).
- 15 H. Seki and T. J. Chuang, Solid State Commun. 44, 473 (1983).
- 16 M. Mashni and P. Hess, Chem. Phys. Lett. 77, 541 (1981).
- 17 M. Mashni and Hess, Appl. Phys. B29, 205 (1982).
- 18 B. Schäfer and Hess, Chem. Phys. Lett. 705, 563 (1984).
- 19 J. Heidberg, I. Hussla, E. Hoefs, H. Stein, and A. Nestmann, Rev. Sci. Instrum. 49, 1571 (1978).
- 20 J. Heidberg, H. Stein, and E. Hoefs, Ber. Bunsenges. Phys. Chem. 121, 145 (1981).
- 21 D. R. Burgess, Jr., I. Hussla, P. C. Stair, R. Viswanathan; and E. Weitz, Rev. Sci. Instrum. 55, 1771 (1984).
- 22 I. Hussla and T. J. Chuang, Symposium Laser Controlled Chemical Processing of Surfaces 1983, Boston, Massachusetts, U.S.A., Materials Research Society Proceedings, eds. A. Wayne Johnson and D. J. Ehrlic (North Holland 1984), p. 341.
- 23 T. J. Chuang and I. Hussla, Phys. Rev. Lett. 52, 2045 (1984).
- 24
T. J. Chuang and
I. Hussla,
in: “Dynamics on Surfaces”,
eds. B. Pullman et al.
(Reidel Publishing, Dortrecht, Holland),
1984,
p. 313.
10.1007/978-94-009-5237-9_24 Google Scholar
- 25 T. J. Chuang, H. Seki, and I. Hussla, Proc. Int. Conf. on Spectroscopic Studies of Adsorbates on Solid Surfaces, Nishinomiya (Japan), 1984, Surf. Sci. in press.
- 26 I. Hussla, H. Seki, T. J. Chuang, Z. Gortel, H.-J. Kreuzer, and P. Piercy, to be published.
- 27 H. J. Kreuzer and D. N. Lowry, Chem. Phys. Lett. 78, 50 (1981).
- 28 Z. W. Gortel, H. J. Kreuzer, P. Piercy, and R. Teshima, Phys. Rev. B27, 5066 (1983).
- 29 Z. W. Gortel, H. J. Kreuzer, P. Piercy, and R. Teshima, Phys. Rev. B28, 2113 (1983).
- 30 T. J. Chuang, Surf. Sci. Rep. 3, 1 (1983).
- 31 D. Lackey, M. Surman, and D. A. King, Vacuum 33, 867 (1982).
- 32 D. C. McKean and P. N. Schatz, J. Chem. Phys. 24, 316(1956).
- 33 P. Pulay and W. Meyer, J. Chem. Phys. 57, 3337 (1972).
- 34 W. M. A. Smit and T. van Dam, J. Chem. Phys. 72, 3658 (1980).
- 35 T. G. Roberts, Rev. Sci. Instrum. 47, 257 (1976).
- 36 H. Coufal, Appl. Phys. Lett. 44, 59 (1984).
- 37 Z. W. Gortel, H. J. Kreuzer, M. Schaff, and G. Wedler, Surf. Sci. 143, 287 (1984).
- 38 J. D. Campell, G. Hancock, J. B. Halpern, and K. H. Welge, Chem. Phys. Lett. 44, 404 (1976).