Laser Flash Photolysis of HCIO, CIO⁻, HBrO, and BrO⁻ in Aqueous Solution. Reactions of Cl- and Br-Atoms

Ulrik K. Kläning,

Ulrik K. Kläning

Chemistry Department, University of Aarhus, Langelandsgade 140, DK-8000 Aarhus C, Denmark

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Thomas Wolff,

Thomas Wolff

Universität Siegen, Physikalische Chemie, D-5900 Siegen 21, Federal Republic of Germany

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Ulrik K. Kläning,

Ulrik K. Kläning

Chemistry Department, University of Aarhus, Langelandsgade 140, DK-8000 Aarhus C, Denmark

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Thomas Wolff,

Thomas Wolff

Universität Siegen, Physikalische Chemie, D-5900 Siegen 21, Federal Republic of Germany

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First published: März 1985

https://doi.org/10.1002/bbpc.19850890309

Citations: 257

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Abstract

Spectra and rate constants of reactions were measured of chlorine and bromine atoms formed by photolysis of aqueous solutions of hypochlorous and hypobromous acids and their salts with light of wavelength 248. 5 and 308 nm. Chlorine and bromine atoms in aqueous solution behave like weak oxygen acids showing the pKa-values 5.1 and 10.5, respectively. Exchanges of water molecules bound to the halogen atoms are fast processes.

Reference

1 G. G. Jayson, B. J. Parson, and A. J. Swallow, J. Chem. Soc. Faraday Trans. I 69, 1597 (1973).
10.1039/f19736901597
CAS Google Scholar
2 D. Zchavi and J. Rabani, J. Phys. Chem. 76, 312 (1972).
10.1021/j100647a006
Web of Science® Google Scholar
3 D. Behar, J. Phys. Chem. 76, 1815 (1972).
10.1021/j100657a004
CAS Web of Science® Google Scholar
4 A. Mamou, J. Rabani, and D. Behar, J. Phys. Chem. 81, 1447 (1977).
10.1021/j100530a003
CAS Web of Science® Google Scholar
5 A. Treinin and E. Hayon, J. Am. Chem. Soc. 97, 1716 (1975).
10.1021/ja00840a016
CAS Web of Science® Google Scholar
6 U. K. Kläning, K. Sehested, and T. Wolff, J. Chem. Soc. Faraday Trans. I 80, 2969 (1984).
10.1039/f19848002969
Web of Science® Google Scholar
7 H. A. Schwarz and R. W. Dodson, J. Phys. Chem. 88, 3643 (1984);
10.1021/j150660a053
CAS Web of Science® Google Scholar
U. K. Kläning, K. Sehested, and J. Holcman, J. Phys. Chem. 89 (in press).
Google Scholar
8 D. D. Wayman, W. H. Evans, V. B. Parker, R. H. Schumm, I. Halow, S. M. Bailey, K. L. Churney, and R. L. Nuttall, J. Phys. Chem. Ref. Data 11, 1982 Suppl. No. 2.
Google Scholar
9 G. V. Buxton and M. S. Subhani, J. Chem. Soc. Faraday Trans. I 68, 947 (1972).
10.1039/f19726800947
CAS Web of Science® Google Scholar
10 G. V. Buxton, F. S. Dainton, and F. Wilkinson, Chem. Commun. 11, 320 (1966).
Google Scholar
11 E. F. Caldin, Fast Reaction in Solution, Blackwell Scientific Publications Oxford 1964.
Google Scholar
12 R. Wilbrandt, N. H. Jensen, A. H. Sillesen, and K. B. Hansen, Chem. Phys. Lett. 106, 503 (1984).
10.1016/0009-2614(84)85371-3
CAS Web of Science® Google Scholar
13 W. F. Howard and L. Andrews, Inorg. Chem. 14, 767 (1975).
10.1021/ic50146a013
CAS Web of Science® Google Scholar

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Volume89, Issue3

März 1985

Pages 243-245

Laser Flash Photolysis of HCIO, CIO⁻, HBrO, and BrO⁻ in Aqueous Solution. Reactions of Cl- and Br-Atoms

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Laser Flash Photolysis of HCIO, CIO−, HBrO, and BrO− in Aqueous Solution. Reactions of Cl- and Br-Atoms

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Laser Flash Photolysis of HCIO, CIO⁻, HBrO, and BrO⁻ in Aqueous Solution. Reactions of Cl- and Br-Atoms