Fabrication of PEI-grafted porous polymer foam for CO2 capture
Jingqian Deng
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorZuolong Liu
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorCorresponding Author
Zhongjie Du
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Jiangsu 213164, People's Republic of China
Correspondence to: Z. Du ([email protected]) and C. Zhang ([email protected])Search for more papers by this authorWei Zou
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Jiangsu 213164, People's Republic of China
Search for more papers by this authorCorresponding Author
Chen Zhang
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Correspondence to: Z. Du ([email protected]) and C. Zhang ([email protected])Search for more papers by this authorJingqian Deng
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorZuolong Liu
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Search for more papers by this authorCorresponding Author
Zhongjie Du
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Jiangsu 213164, People's Republic of China
Correspondence to: Z. Du ([email protected]) and C. Zhang ([email protected])Search for more papers by this authorWei Zou
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Jiangsu 213164, People's Republic of China
Search for more papers by this authorCorresponding Author
Chen Zhang
Key Laboratory of Carbon Fiber and Functional Polymers (Beijing University of Chemical Technology), Ministry of Education; College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China
Correspondence to: Z. Du ([email protected]) and C. Zhang ([email protected])Search for more papers by this authorABSTRACT
A polymer foam material with both the open-cell porous structure and the polyethylenemine (PEI)-grafted inner face was constructed for CO2 capture. The porous poly(tert-butyl acrylate) foam was first prepared via a concentrated emulsion polymerization, and then the carboxyl groups were introduced on the interface of porous polymer after the hydrolysis reaction. Subsequently, the surface of the foam was grafted with PEI, and finally the PEI-grafted porous polymer foam designed as a CO2 capture material was obtained. The structures of the foams were characterized by infrared spectroscopy, EDS, and SEM. The CO2 adsorption properties were measured by adsorption/desorption cycles. As a result, the polymer foam contained a large number of amine groups (13.9 wt % N), and therefore possessed a high CO2 adsorption capacity (5.91 mmol g−1 at 40°C and 100 kPa). In addition, they also exhibited high CO2 adsorption rate, good selectivity for CO2-N2 separation, and good stability according to CO2 cyclic adsorption/desorption test. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47844.
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