Facile preparation of Cu(I) impregnated MIL-101(Cr) and its use in a mixed matrix membrane for olefin/paraffin separation
Jung Pyo Jung
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
J. P. Jung and M. J. Kim contributed equally to this work.
Search for more papers by this authorMin June Kim
Department of Integrated Engineering, Yonsei University, Seoul 120-749, South Korea
J. P. Jung and M. J. Kim contributed equally to this work.
Search for more papers by this authorCorresponding Author
Youn-Sang Bae
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
Department of Integrated Engineering, Yonsei University, Seoul 120-749, South Korea
Correspondence to: J. H. Kim (E-mail: [email protected]) and Y.-S. Bae (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Jong Hak Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
Correspondence to: J. H. Kim (E-mail: [email protected]) and Y.-S. Bae (E-mail: [email protected])Search for more papers by this authorJung Pyo Jung
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
J. P. Jung and M. J. Kim contributed equally to this work.
Search for more papers by this authorMin June Kim
Department of Integrated Engineering, Yonsei University, Seoul 120-749, South Korea
J. P. Jung and M. J. Kim contributed equally to this work.
Search for more papers by this authorCorresponding Author
Youn-Sang Bae
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
Department of Integrated Engineering, Yonsei University, Seoul 120-749, South Korea
Correspondence to: J. H. Kim (E-mail: [email protected]) and Y.-S. Bae (E-mail: [email protected])Search for more papers by this authorCorresponding Author
Jong Hak Kim
Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, South Korea
Correspondence to: J. H. Kim (E-mail: [email protected]) and Y.-S. Bae (E-mail: [email protected])Search for more papers by this authorABSTRACT
Cu(I) impregnated MIL-100(Cr) [denoted Cu@MIL-101(Cr)] is fabricated by a facile method and utilized in mixed matrix membranes (MMMs) for propylene/propane separation. Cu(I) is prepared from a CuCl2 solution via mild reduction process using sodium sulfite as the reducing agent. The filler is incorporated into a polystyrene-b-polybutadiene-b-polystyrene (SBS) block copolymer matrix to form MMMs. As a result, both the permeability and selectivity of propylene/propane are improved after Cu(I) impregnation. The best performance is obtained for SBS/Cu@MIL-101(Cr) MMM, and these values represent 17% and 54% improvements compared to those of SBS/MIL-101(Cr) MMM, respectively. This result is attributed to the π-complexation of the loaded Cu(I) by propylene gas, indicating that Cu@MIL-101(Cr) with internal Cu(I) and a high pore volume acted as an effective filler to aid propylene/propane separation. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46545.
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