Article
Highly effective organometallic-mediated radical polymerization of vinyl acetate using alumina-supported Co(acac)2 catalyst: A case study of adsorption and polymerization
Mohammad Ali Semsarzadeh,
Alireza Sabzevari,
Corresponding Author
Mohammad Ali Semsarzadeh
Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, P.O. Box: 14155/143, Tehran, Iran
Correspondence to: M. A. Semsarzadeh (E-mail: [email protected])Search for more papers by this authorAlireza Sabzevari
Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, P.O. Box: 14155/143, Tehran, Iran
Search for more papers by this authorMohammad Ali Semsarzadeh,
Alireza Sabzevari,
Corresponding Author
Mohammad Ali Semsarzadeh
Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, P.O. Box: 14155/143, Tehran, Iran
Correspondence to: M. A. Semsarzadeh (E-mail: [email protected])Search for more papers by this authorAlireza Sabzevari
Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, P.O. Box: 14155/143, Tehran, Iran
Search for more papers by this authorABSTRACT
An alumina support system for cobalt(II) acetylacetonate (Co(acac)2) catalyst was studied for the cobalt-mediated radical polymerization (CMRP) of vinyl acetate (VAc). We report a simple but efficient technique to produce this supported catalysts through the adsorption of Co(acac)2 on the surface of alumina particles. Moreover, kinetic and thermodynamic study of Co(acac)2 adsorption on the alumina support were conducted and the influence of effective parameters were investigated. It was found that using alumina-supported Co(acac)2 for radical polymerization of VAc yields polymers with controlled molecular weight, narrow molecular weight distribution, and high purity. For the alumina-supported CMRP, changing the polymerization mechanism and domination of termination pathway compared to degenerate transfer pathway resulted in a 2.5 times increase in polymerization rate (kap) and a drop in induction time while maintaining a good control of the VAc polymerization. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46057.
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