Effect of nucleating agents on the crystallization behavior and heat resistance of poly(l-lactide)
Xiuqin Zhang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorLingyan Meng
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorGen Li
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorNingning Liang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorJing Zhang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorZhiguo Zhu
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorCorresponding Author
Rui Wang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Correspondence to: R. Wang (E-mail: [email protected])Search for more papers by this authorXiuqin Zhang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorLingyan Meng
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorGen Li
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorNingning Liang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorJing Zhang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorZhiguo Zhu
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Search for more papers by this authorCorresponding Author
Rui Wang
School of Materials Science & Engineering, Beijing Institute of Fashion Technology, Beijing, 100029 China
Correspondence to: R. Wang (E-mail: [email protected])Search for more papers by this authorABSTRACT
Poly (l-lactide) (PLLA) blends with various nucleators were prepared by melt processing. The effect of different nucleators on the crystallization behavior and heat resistance as well as thermomechanical properties of PLLA was studied systematically by differential scanning calorimetry, X-ray diffraction, heat deflection temperature tester, and dynamic mechanical analysis. It was found that poly(d-lactide), talcum powder (Talc), a multiamide compound (TMC-328, abbreviated as TMC) can significantly improve the crystallization rate and crystallinity of PLLA, thus improving thermal–resistant property. The heat deflection temperature of nucleated PLLA can be as high as 150°C. The storage modulus of nucleated PLLA is higher than that of PLLA at the temperature above Tg of PLLA. Compared with other nucleating agents, TMC was much more efficient at enhancing the crystallization of PLLA and the PLLA containing TMC showed the best heat resistance. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 42999.
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February 20, 2016
