Preparation of superhydrophobic surfaces by cauliflower-like polyaniline
Jin-Feng Cui
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorXue-Mei Bao
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorHan-Xue Sun
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorJin An
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorJun-Hong Guo
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorBao-Ping Yang
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorCorresponding Author
An Li
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Correspondence to: A. Li (E-mail: [email protected])Search for more papers by this authorJin-Feng Cui
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorXue-Mei Bao
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorHan-Xue Sun
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorJin An
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorJun-Hong Guo
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorBao-Ping Yang
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Search for more papers by this authorCorresponding Author
An Li
Department of Chemical Engineering, College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050 People's Republic of China
Correspondence to: A. Li (E-mail: [email protected])Search for more papers by this authorABSTRACT
Cauliflower-like polyaniline (PANI) was successfully prepared using an interfacial polymerization method. By modification with polydimethylsiloxane (PDMS) using chemical vapor deposition method, the surface wettability of cauliflower-like PANI can be tailored to be superhydrophobic with a water contact angle of 160.4°. The deposition of the low-surface-energy silicon coating originated from PDMS pyrolysis on the cauliflower-like PANI was confirmed by X-ray photoelectron spectroscopy and Fourier Transform Infrared Spectroscopy. The changes in thermal stability and conductivity of the as-prepared PANI before and after PDMS treatment were also investigated by thermogravimetric analysis and using a four-probe method. Compared with nanofiber-shaped PANI by electrodepositing polymerization, the PDMS-treated cauliflower-like PANI has superior surface wettability. Our study may open a new way for fabrication of superhydrophobic surfaces by developing novel nanostructured PANI. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39767.
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January 15, 2014
