Volume 128, Issue 4 pp. 2375-2384

Article

Study on the preparation of Eu(Pht)₃Phen/SBA-15 hybrids and photoluminescence properties of silicone rubber composites with the hybrids

Shengjie Xu,

Shengjie Xu

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Wentan Ren,

Corresponding Author

Wentan Ren

[email protected]

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China===Search for more papers by this author

Yong Zhang,

Yong Zhang

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Yinxi Zhang,

Yinxi Zhang

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Shengjie Xu,

Shengjie Xu

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Wentan Ren,

Corresponding Author

Wentan Ren

[email protected]

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China===Search for more papers by this author

Yong Zhang,

Yong Zhang

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Yinxi Zhang,

Yinxi Zhang

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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First published: 25 July 2012

https://doi.org/10.1002/app.38280

Citations: 4

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Abstract

In this work, Eu(Pht)₃Phen/SBA-15 hybrids were prepared by solution mixing and their morphologies and structures were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), nitrogen adsorption–desorption and transmission electronic microscopy (TEM). The results showed that Eu(Pht)₃Phen was successfully incorporated into the channels and assembled onto the surface of SBA-15 and the long range ordered structure of SBA-15 was preserved. The silicone rubber composites with Eu(Pht)₃Phen/SBA-15 hybrids were obtained by mechanical blending, and their morphologies and photoluminescence properties were studied. The results showed that the photoluminescence intensities of the composites with the hybrids increased as the content of the hybrids increased. The composite with the hybrids showed higher photoluminescence intensity and longer lifetime compared to the silicone rubber compounded with Eu(Pht)₃Phen (Eu(Pht)₃Phen/silicone rubber composite), Eu(Pht)₃Phen and SBA-15 ([Eu(Pht)₃Phen+SBA-15]/silicone rubber composite). Judd-Ofelt theory was used to investigate the local environment of Eu³⁺ ions in the silicone rubber composites. The photoluminescence quantum efficiency of the silicone rubber composite with Eu(Pht)₃Phen/SBA-15 hybrids was calculated to be 31.0%, higher than that of Eu(Pht)₃Phen/silicone rubber composite (26.4%) and [Eu(Pht)₃Phen+SBA-15]/silicone rubber composite (25.4%). The enhancement in photoluminescence intensity and increase in lifetime and photoluminescence quantum efficiency could be attributed to the rigid structure of SBA-15 which reduced the nonradiative transition rate and the improvement of the dispersion of the hybrids in the composites. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

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Volume128, Issue4

Special Issue:Elastomers

15 May 2013

Pages 2375-2384

Study on the preparation of Eu(Pht)₃Phen/SBA-15 hybrids and photoluminescence properties of silicone rubber composites with the hybrids

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Study on the preparation of Eu(Pht)3Phen/SBA-15 hybrids and photoluminescence properties of silicone rubber composites with the hybrids

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Study on the preparation of Eu(Pht)₃Phen/SBA-15 hybrids and photoluminescence properties of silicone rubber composites with the hybrids