Preparation and characterization of polyacrylate/polymerized rosin composite emulsions by seeded semicontinuous emulsion polymerization
Pingxu Chen
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorCorresponding Author
Xingrong Zeng
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China===Search for more papers by this authorHongqiang Li
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorXiaodan Liu
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorDandan Liu
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorXiaolan Li
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorPingxu Chen
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorCorresponding Author
Xingrong Zeng
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China===Search for more papers by this authorHongqiang Li
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorXiaodan Liu
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorDandan Liu
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorXiaolan Li
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China
Search for more papers by this authorAbstract
Polyacrylate/polymerized rosin composite emulsions were prepared by seeded semicontinuous emulsion polymerization of acrylate monomers in which polymerized rosin was dissolved. The effects of polymerized rosin content on the polymerization stability, monomer conversion, polymer structure, and adhesive properties were studied. Polyacrylate/polymerized rosin composites were characterized by gel permeation chromatograph (GPC), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and thermogracvimetry (TG). The results showed that with an increase of polymerized rosin content from 0 to 6 wt %, gel fraction and sol molecular weight decreased obviously but monomer conversion was basically unchanged. In contrast, with a further increase of polymerized rosin content, the decreasing rates of gel fraction, and sol molecular weight were slowed down. Meanwhile, monomer conversion decreased remarkably. Moreover, interface failure changed into cohesive failure after the addition of polymerized rosin, and the peel adhesion and shear resistance of composite latex films declined with the increase of polymerized rosin content. Thermal analysis showed that polymerized rosin and polyacrylate were compatible and the composite latex films had good thermal stability. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
References
- 1 Bicu, A.; Mustata, F. J Polym Sci A Polym Chem 2005, 43, 6308.
- 2 Atta, A. M.; Elsaeed, A. M.; Farag, R. K.; El-Saeed, S. M. React Funct Polym 2007, 67, 549.
- 3 Bicu, I.; Mustata, F. J Polym Sci A Polym Chem 2007, 45, 5979.
- 4 Do, H. S.; Park, J. H.; Kim, H. J. J Appl Polym Sci 2009, 111, 1172.
- 5 Wang, J. F.; Lin, M. T.; Wang C. P.; Chu, F. X. J Appl Polym Sci 2009, 113, 3757.
- 6 Hayashi, S.; Kim, H. J.; Kajiyama, M.; Ono, H.; Mizumachi, H.; Zufu, Z. J Appl Polym Sci 1999, 71, 651.
- 7 Fujita, M.; Kajiyama, M.; Takemura, A.; Ono, H.; Mizumachi, H.; Hayashi, S. J Appl Polym Sci 1998, 70, 777.
- 8 Kim, D. J.; Kim, H. J.; Yoon, G. H. J Adhes Sci Technol 2004, 18, 1783.
- 9 Atta, A. M.; Mansour, R.; Abdou, M. I.; Sayed, A. M. Polym Adv Technol 2004, 15, 514.
- 10 Lee, J. S.; Hong, S. I. Eur Polym J 2002, 38, 387.
- 11 Canetta, E.; Marchal, J.; Lei, C. H.; Deplace, F.; Konig, A. M.; Creton, C.; Ouzineb, K.; Keddie, J. L. Langmuir 2009, 25, 11021.
- 12 Song, D. Y.; Zhang, W.; Melby, E. G.; Gupta, R. K. Meas Sci Technol 2008, 19, 1.
- 13 Yoo, Y.; Hong, G. H.; Hur, S. R.; Kim, Y. S.; Lee, S. G.; Kim, H. J.; Lee, J. H. J Appl Polym Sci 2009, 112, 1587.
- 14 Zhang, J. D.; Yang, M. J.; Zhu, Y. R.; Yang, H. Polym Inter 2006, 55, 951.
- 15 Guo, T. Y.; Chen, X.; Song, M. D.; Zhang, B. H. J Appl Polym Sci 2006, 100, 1824.
- 16 Foster, A. B.; Lovell, P. A.; Rabjohns, M. A. Polymer 2009, 50, 1654.
- 17 Simal, F.; Jeusette, M.; Leclere, P.; Lazzaroni, R.; Roose, P. J Adhes Sci Technol 2007, 21, 559.
- 18 Wang, T.; Lei, H.; Dalton, A. B.; Creton, C.; Lin, Y.; Fernando, K. A. S.; Sun, Y. P.; Manea, M.; Asua, J. M.; Keddie, J. L. Adv Mater 2006, 18, 2730.
- 19 Wang, T.; Lei, C. H.; Liu, D.; Manea, M.; Asua, J. M.; Creton, C.; Dalton, A. B.; Keddie, J. L. Adv Mater 2008, 20, 90.
- 20 Kim, B. J.; Kim, S.; Kim, S. E.; Kim, H. J.; Kim, S. D. J Adhes Sci Technol 2007, 21, 109.
- 21
Tobing, S. D.;
Klein, A.
J Appl Polym Sci
2000,
76,
1965.
10.1002/(SICI)1097-4628(20000624)76:13<1965::AID-APP14>3.0.CO;2-Y CAS Web of Science® Google Scholar
- 22 Mallegol, J.; Bennett, G.; McDonald, P. J.; Keddie, J. L.; Dupont, O. J Adhes 2006, 82, 217.
- 23 Paiva, A.; Sheller, N.; Foster, M. D.; Crosby, A. J.; Shull, K. R. Macromolecules 2001, 34, 2269.
- 24 Jeusette, M.; Peeterbroeck, S.; Simal, F.; Cossement, D.; Roose, P.; Leclere, P.; Dubois, P.; Hecq, M.; Lazzaroni, R. Eur Polym J 2008, 44, 3931.
- 25 Kim, B. J.; Kim, S. E.; Do, H. S.; Kim, S.; Kim, H. J. Int J Adhes Adhes 2007, 27, 102.
- 26 Chern, C. S. Prog Polym Sci 2006, 31, 443.
- 27 Qu, X. W.; Wang, N. Y.; Lovell, P. A. J Appl Polym Sci 2009, 112, 3030.
- 28 Bakhshi, H.; Bouhendi, H.; Zohuriaan-Mehr, M. J.; Kabiri, K. J Appl Polym Sci 2010, 117, 2771.
- 29 Kohut-Svelko, N.; Pirri, R.; Asua J. M.; Leiza, J. R. J Polym Sci A Polym Chem 2009, 47, 2917.
- 30 Bouvier-Fontes, L.; Pirri, R.; Magnet, S.; Asua, J. M.; Leiza, J. R. Macromolecules 2005, 38, 2722.
- 31 Mishra, S.; Singh, J.; Choudhary, V. J Appl Polym Sci 2010, 115, 549.
- 32 Shamir, D.; Siegmann, A.; Narkis, M. J Appl Polym Sci 2010, 115, 1922.
- 33 Athawale, V. D.; Kulkarni, M. A. Prog Org Coat 2009, 65, 392.
- 34 Garg, S.; Jana, A. K. J Appl Polym Sci 2011, 119, 1383.
- 35 Kajtna, J.; Likozar, B.; Golob, J.; Krajnc, M. Inter J Adhes Adhes 2008, 28, 382.
- 36 Kajtna, J.; Golob, J.; Krajnc, M. Inter J Adhes Adhes 2009, 29, 186.
- 37 Lin, M. T.; Jiang, Y.; Chu, F., X. Chem Ind Forest Prod 2002, 22, 17.
- 38 Plessis, C.; Arzamendi, G.; Leiza, J. R.; Schoonbrood, H. A. S.; Charmot, D.; Asua, J. M. Macromolecules 2001, 34, 5147.
- 39 Gonzalez, I.; Asua, J. A.; Leiza, J. R. Polymer 2007, 48, 2542.
- 40 Chauvet, J.; Asua, J. A.; Leiza, J. R. Polymer 2005; 46, 9555.
- 41 Liu, X. Q.; Xin, W. B.; Zhang, J. W. Green Chem 2009, 11, 1018.
- 42 Wang, H. H.; Wang, H. W.; Zhou, G. Y. Polym Int 2011, 60, 557.
- 43 Zheng, W.; He, L.; Liang, J. Y.; Chang, G.; Wang, N. J Appl Polym Sci 2011, 120, 1152.
- 44 Xiao, X. Y.; Xu, R. J Appl Polym Sci 2011, 119, 1576.
- 45 Flory, P. J. Principles of Polymer Chemistry, 15th ed.; Cornell University Press: Ithaca, New York, 1992.
- 46 Ren, T. R.; Li, Y. H. Rosin Chemistry and its Applicants (in Chinese), 2nd ed.; Chemical Industry Press: Beijing, 2007.
Citing Literature
