Studies on graft copolymerization of cyclohexyl methacrylate onto 1,2-polybutadiene

Der-Jang Liaw,

Der-Jang Liaw

Department of Chemical Engineering, National Taiwan Institute of Technology Taipei, Taiwan 10772, Republic of China

Search for more papers by this author

Lei-Li Lin,

Lei-Li Lin

Department of Chemical Engineering, National Taiwan Institute of Technology Taipei, Taiwan 10772, Republic of China

Search for more papers by this author

Der-Jang Liaw,

Der-Jang Liaw

Department of Chemical Engineering, National Taiwan Institute of Technology Taipei, Taiwan 10772, Republic of China

Search for more papers by this author

Lei-Li Lin,

Lei-Li Lin

Department of Chemical Engineering, National Taiwan Institute of Technology Taipei, Taiwan 10772, Republic of China

Search for more papers by this author

First published: March 1989

https://doi.org/10.1002/app.1989.070370719

Citations: 4

About

PDF

Tools

Share a link

Email
Wechat
Bluesky

Abstract

The free radical grafting of cyclohexyl methacrylate (CMA) onto 1,2-polybutadiene (1,2-PBD) in benzene solution at 60°C was studied. The graft copolymer was characterized by IR, NMR, DSC, and intrinsic viscosity measurements. The polymerization of CMA shows normal kinetic behavior when the PBD concentration is kept below 1.0 monomer mol/L. The rate of grafting was determined at different reaction times, monomer concentrations, initiator concentrations, backbone concentrations, temperatures, and concentrations of the zinc chloride additive. The performance of the graft copolymer used as adhesive was also investigated for bonding of PVC/PVC film.

References

1 A. Brydon, G. M. Burnett, and G. G. Cameron, J. Polym. Sci., Polym. Chem. Ed., 11, 3255 (1973)
10.1002/pol.1973.170111218
CAS Web of Science® Google Scholar
2 A. Brydon, G. M. Burnett, and G. G. Cameron, J. Polym. Sci., Polym. Chem. Ed., 12, 1011 (1974)
10.1002/pol.1974.170120509
CAS Web of Science® Google Scholar
3 G. G. Cameron and M. Y. Qureshi, J. Polym. Sci., Polym. Chem. Ed., 18, 2143 (1980).
10.1002/pol.1980.170180710
CAS Web of Science® Google Scholar
4 G. G. Cameron and M. Y. Qureshi, J. Polym. Sci., Polym. Chem. Ed., 18, 3149 (1980).
10.1002/pol.1980.170181102
Web of Science® Google Scholar
5 Y. Minoura, S. Yamashita, H. Yamaguchi, S. Khojiya, T. Yokoyama, and K. Yamaguchi, Nippon Gomu Kyokaishi, 54, 166 (1981) (in Japanese).
10.2324/gomu.54.166
CAS Google Scholar
6 P. Manaresi, V. Passalacqua, and F. Pilati, Polymer, 16, 520 (1975).
10.1016/0032-3861(75)90011-7
CAS Web of Science® Google Scholar
7 A. Gasperowicz and W. Taskwski, J. Polym. Sci., Polym. Chem. Ed., 14, 2875 (1976).
10.1002/pol.1976.170141204
CAS Web of Science® Google Scholar
8 I. Yamaji, S. Hattori, and K. Aoki, Kobunshi Ronbuushu, 33(2), 102 (1976) (in Japanese).
10.1295/koron.33.102
CAS Web of Science® Google Scholar
9 I. Skeist, Handbook of Adhesives, 2nd ed., Van Nortrand Reinhold, New York, 1977, pp. 242–254.
Google Scholar
10 A. Morduchowitz, S. Valley, and J. T. Nolan, U.S. Pat. 3,370,009 (1968).
Google Scholar
11 S. G. Turley, Am. Chem. Soc., Org. Coatings Plast. Chem., 27, 453 (1967);
Google Scholar
Am. Chem. Soc. Polym. Prepr., 8, 1524 (1967).
Web of Science® Google Scholar
12 J. van Turnhout, Polymer J. (Jpn.), 2, 173 (1971).
10.1295/polymj.2.173
CAS Web of Science® Google Scholar
13 J. A. Shetter, J. Polym. Sci., B, 1, 209 (1963).
10.1002/pol.1963.110010503
CAS Web of Science® Google Scholar
14 Toa Gosei Chemical Industry Co., Ltd., Japan Kokai Tokkyo Koho 45-9664 (1970).
Google Scholar
15 D. J. Liaw and K. C. Chung, Makromol. Chem., 184, 29 (1983).
10.1002/macp.1983.021840104
CAS Web of Science® Google Scholar
16 D. J. Liaw and K. C. Chung, J. Chinese Inst. Chem. Eng., 13, 145 (1982).
CAS Google Scholar
17 S. P. Rao and M. Santappa, J. Polym. Sci., Part A-1, 6, 95 (1968).
10.1002/pol.1968.150060110
CAS Web of Science® Google Scholar
18 M. Kitayama and O. Vogl, J. Macromol. Sci. Chem., A19(3), 375 (1983).
10.1080/10601328308056522
CAS Web of Science® Google Scholar
19 K. Kaleem, C. R. Reddy, and S. Rajadurai, J. Appl. Polym. Sci., 26, 2305 (1981).
10.1002/app.1981.070260717
CAS Web of Science® Google Scholar
20 D. Mohan, G. Radhakrishnan, and S. Rajadurai, J. Appl. Polym. Sci., 29, 329 (1984).
10.1002/app.1984.070290131
CAS Web of Science® Google Scholar
21 A. Geogre, G. Radhakrishnan, and K. Thomas, J. Polym. Sci., Polym. Chem. Ed., 23, 2865 (1985).
10.1002/pol.1985.170231114
Web of Science® Google Scholar
22 A. Geogre, G. Radhakrishnan, and K. Joseph, Eur. Polym. J., 21(12), 1081 (1985).
10.1016/0014-3057(85)90218-6
Web of Science® Google Scholar
23 A. Geogre, G. Radhakrishnan, and K. T. Joseph, Angew. Makromol. Chem., 128, 173 (1984).
10.1002/apmc.1984.051280110
Web of Science® Google Scholar
24 Japan Synthetic Rubber Company catalogue.
Google Scholar
25 L. J. Young, Polymer Handbook, 2nd ed., J. Brandrup and E. H. Immergut, Eds., Wiley, New York, 1975, Chap. 3, p. 147.
Web of Science® Google Scholar
26 P. L. Nayak, S. Lenka, and M. K. Mishra, J. Polym. Sci., Polym. Chem. Ed., 19, 839 (1973).
10.1002/pol.1981.170190323
Web of Science® Google Scholar
27 S. Lenka, J. Appl. Polym. Sci., 27, 1417 (1982).
10.1002/app.1982.070270431
CAS Web of Science® Google Scholar
28 S. Lenka, P. L. Nayak, and A. P. Das, J. Appl. Polym. Sci., 30, 2753 (1985).
10.1002/app.1985.070300704
CAS Web of Science® Google Scholar
29 S. Lenka and P. L. Nayak, J. Polym. Sci., Polym. Chem. Ed., 21, 1871 (1983).
10.1002/pol.1983.170210628
CAS Web of Science® Google Scholar
30 P. L. Nayak, S. Lenka, and M. K. Mishra, J. Macromol. Sci. Chem., A16(4), 843 (1981).
10.1080/00222338108056830
CAS Web of Science® Google Scholar

Citing Literature

Volume37, Issue7

March 1989

Pages 1993-2006

Studies on graft copolymerization of cyclohexyl methacrylate onto 1,2-polybutadiene

Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Studies on graft copolymerization of cyclohexyl methacrylate onto 1,2-polybutadiene

Abstract

References

Citing Literature

References

Related

Information