Volume 22, Issue 6 pp. 1643-1654
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Swelling and glass transition relations for epoxy matrix material in humid environments

E. Lee McKague Jr.

E. Lee McKague Jr.

General Dynamics, Fort Worth Division, Fort Worth, Texas 76101

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Jack D. Reynolds

Jack D. Reynolds

General Dynamics, Fort Worth Division, Fort Worth, Texas 76101

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John E. Halkias

John E. Halkias

General Dynamics, Fort Worth Division, Fort Worth, Texas 76101

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First published: June 1978
Citations: 190

Abstract

An experimental investigation has established coherent data sets describing effects of moisture absorption upon swelling and glass transition of an epoxy resin. Equilibrium moisture absorption levels and resultant swelling can be represented by power law functions of relative humidity and quantity of absorbed moisture, respectively. Depression of glass transition temperature is shown to be described by a relationship derived from free-volume theory.

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