Volume 81, Issue 6 pp. 1310-1315

Poly(styrene-alt-maleic acid)–metal complexes with divalent metal ions. synthesis, characterization, and physical properties

Bernabé L. Rivas

Corresponding Author

Bernabé L. Rivas

Faculty of Chemistry, University of Concepción, Casilla 160-C, Concepción, Chile

Faculty of Chemistry, University of Concepción, Casilla 160-C, Concepción, Chile===Search for more papers by this author
Gloria V. Seguel

Gloria V. Seguel

Faculty of Chemistry, University of Concepción, Casilla 160-C, Concepción, Chile

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Kurt E. Geckeler

Kurt E. Geckeler

Laboratory of Applied Macromolecular Chemistry, Department of Materials Science and Engineering, Kwangju Institute of Science and Technology, 1 Oryong-dong, Puk-gu, Kwangju 500-712, South Korea

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First published: 23 May 2001
Citations: 13

Abstract

Polymer–metal complexes of the alternating copolymer styrene and maleic acid with Cu(II), Co(II), Ni(II), and Zn(II) were synthesized and characterized by elemental analysis, infrarred and electronic spectra, and thermogravimetry. In addition, magnetic measurements were performed and the electrical conductivity was studied at different temperatures. Semiempirical calculations at the PM 3 level were carried out to elucidate the geometrical arrangement of the polychelates. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1310–1315, 2001

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