Volume 92, Issue 1 pp. 171-177

Doping level change of polyaniline film during its electrochemical growth process

Chen Liu,

Chen Liu

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

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Jiaxin Zhang,

Jiaxin Zhang

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

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Gaoquan Shi,

Corresponding Author

Gaoquan Shi

[email protected]

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China===Search for more papers by this author

Feng'en Chen,

Feng'en Chen

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

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Chen Liu,

Chen Liu

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

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Jiaxin Zhang,

Jiaxin Zhang

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

Search for more papers by this author

Gaoquan Shi,

Corresponding Author

Gaoquan Shi

[email protected]

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China===Search for more papers by this author

Feng'en Chen,

Feng'en Chen

Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China

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First published: 27 January 2004

https://doi.org/10.1002/app.13706

Citations: 39

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Abstract

Polyaniline (PANI) films doped with hydrochloric acid have been electrochemically deposited on mirrorlike platinum electrode surfaces by a cyclic voltammogram method. The Raman spectra of doped PANI films were investigated by excitation with a 633- or 785-nm laser beam. It was found that the overall features of the Raman spectra depend strongly on the film thickness, due mainly to that the doping level of PANI film increases during the film-growth process. X-ray photoelectron spectroscopic (XPS) analysis and ultraviolet (UV)-visible absorption spectrum results also confirmed this finding. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 171–177, 2004

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Volume92, Issue1

5 April 2004

Pages 171-177

Doping level change of polyaniline film during its electrochemical growth process

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Doping level change of polyaniline film during its electrochemical growth process

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