Mechanism of nickel extraction from sulfuric acid medium by synthesized α-aminophosphonate derivative
Dongmei He
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorLi Zeng
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorGuiqing Zhang
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorQinggang Li
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorWenjuan Guan
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorCorresponding Author
Zuoying Cao
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Correspondence
Zuoying Cao and Shengxi Wu, School of Metallurgy and Environment, Central South University, Changsha 410083, China.
Email: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Shengxi Wu
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Correspondence
Zuoying Cao and Shengxi Wu, School of Metallurgy and Environment, Central South University, Changsha 410083, China.
Email: [email protected]; [email protected]
Search for more papers by this authorDongmei He
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorLi Zeng
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorGuiqing Zhang
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorQinggang Li
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorWenjuan Guan
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Search for more papers by this authorCorresponding Author
Zuoying Cao
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Correspondence
Zuoying Cao and Shengxi Wu, School of Metallurgy and Environment, Central South University, Changsha 410083, China.
Email: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Shengxi Wu
School of Metallurgy and Environment, Central South University, Changsha, 410083 China
Laboratory of Metallurgical Separation Science and Engineering of Central South University, Changsha, 410083 China
Correspondence
Zuoying Cao and Shengxi Wu, School of Metallurgy and Environment, Central South University, Changsha 410083, China.
Email: [email protected]; [email protected]
Search for more papers by this authorAbstract
A new compound, α-aminophosphonate derivative containing pyridine ring (PPDE), was designed and synthesized as an extractant for the separation of nickel from metal impurities. Over 94.5% of Ni (II) extraction from sulfuric acid solution was achieved by using PPDE with an equilibrium pH of 4.02. Meanwhile, high separation coefficients of 23.8 for Ni to Co, 84.9 for Ni to Mn, 254.1 for Ni to Ca and 696.7 for Ni to Mg, respectively, were obtained. It was noted that PPDE exhibited an excellent regenerability, and the extraction of Ni with the recycled organic phase ranged from 92.5% to 93.9% during six circulations. The extracted nickel complex was determined as [Ni (PPDE)2(DNNSA−)2(H2O)4], which was supported by the data obtained from Fourier transform-infrared, UV–Vis and electrospray ionization-mass spectrometry spectra.
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