Review
Molecular Engineering of Metal Complexes for Electrocatalytic Carbon Dioxide Reduction: From Adjustment of Intrinsic Activity to Molecular Immobilization
Zhi-Wen Yang,
Jin-Mei Chen,
Li-Qi Qiu,
Wen-Jun Xie,
Prof. Dr. Liang-Nian He,
Zhi-Wen Yang
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorJin-Mei Chen
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorLi-Qi Qiu
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorWen-Jun Xie
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Liang-Nian He
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorZhi-Wen Yang,
Jin-Mei Chen,
Li-Qi Qiu,
Wen-Jun Xie,
Prof. Dr. Liang-Nian He,
Zhi-Wen Yang
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorJin-Mei Chen
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorLi-Qi Qiu
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorWen-Jun Xie
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Liang-Nian He
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorDedicated to the 60th anniversary of Institute of Elemento-Organic Chemistry, Nankai University.
Graphical Abstract
This Review focuses on molecular catalysts for the electrocatalytic CO2 reduction reaction (ECO2RR) including metal bipyridines and macrocycle complexes, and summarizes the molecular engineering strategies developed to regulate the intrinsic catalytic efficiency and modify the electrode. Guidelines are provided for the rational design of ECO2RR catalytic systems.
Abstract
The electrocatalytic CO2 reduction reaction (ECO2RR) is one promising method for storing intermittent clean energy in chemical bonds and producing fuels. Among various kinds of catalysts for ECO2RR, molecular metal complexes with well-defined structures are convenient for studies of their rational design, structure–reactivity relationships, and mechanisms. In this Review, we summarize the molecular engineering of several N-based metal complexes including Re/Mn bipyridine compounds and metal macrocycles, concluding with general modification strategies to devise novel molecular catalysts with high intrinsic activity. Through physical adsorption, covalent linking, and formation of a periodic backbone, these active molecules can be heterogenized into immobilized catalysts with more practical prospects. Finally, significant challenges and opportunities based on molecular catalysts are discussed.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
Data sharing is not applicable to this article as no new data were created or analyzed in this study.
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