Layered Double Hydroxide-Assisted Fabrication of Prussian Blue Membranes for Precise Molecular Sieving
Qi Bian
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorMu Zhang
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yi Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Liangliang Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorYang Li
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorDr. Chen Wang
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorProf. Gaohong He
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorCorresponding Author
Prof. Yi Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorQi Bian
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorMu Zhang
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yi Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Liangliang Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
These authors contributed equally to this work.
Search for more papers by this authorYang Li
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorDr. Chen Wang
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorProf. Gaohong He
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorCorresponding Author
Prof. Yi Liu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Linggong Road NO. 2, Ganjingzi District, Dalian, 116024 China
Search for more papers by this authorDedicated to Professor Jürgen Caro on the occasion of his 70th birthday
Graphical Abstract
For the first time, we prepared continuous polycrystalline Prussian blue (PB) membrane showing precise dye rejection and monovalent ion discrimination ability. The introduction of a calcined NiFe-CO3 layered double hydroxide buffer layer on the substrate was found to play a paramount role in the formation of PB membrane with desirable microstructure and performance.
Abstract
Prussian Blue (PB), which was first discovered as robust blue-colored pigment in the year 1706, has shown promising prospects in disease treatment, energy conversion, water splitting, and sensing. Relying on the uniform 3.2 Å-sized pore channels as well as high stability in aqueous environments, in this study, we pioneered in situ preparation of polycrystalline PB membranes to justify their dye rejection and metal ion discrimination ability in aqueous environments. Among various factors, the introduction of calcined NiFe layered double hydroxide buffer layers on porous α-Al2O3 substrates was found to play a paramount role in the formation of continuous polycrystalline PB membranes, thereby leading to excellent dye rejection efficiency (>99.0 %). Moreover, prepared PB membranes enabled discriminating different monovalent metal ions (e.g., Li+, Na+, and K+) depending on their discrepancy in Stokes diameters, showing great promise for lithium extraction from smaller-sized metal ions.
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