Guest-Driven Light-Induced Spin Change in an Azobenzene Loaded Metal–Organic Framework
Kai-Ping Xie
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorZe-Yu Ruan
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorBang-Heng Lyu
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorXiao-Xian Chen
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorXue-Wen Zhang
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorGuo-Zhang Huang
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorDr. Yan-Cong Chen
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhao-Ping Ni
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Ming-Liang Tong
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorKai-Ping Xie
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorZe-Yu Ruan
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorBang-Heng Lyu
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorXiao-Xian Chen
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorXue-Wen Zhang
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorGuo-Zhang Huang
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorDr. Yan-Cong Chen
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhao-Ping Ni
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Ming-Liang Tong
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorGraphical Abstract
Guest-driven light-induced spin change (GD-LISC) was firstly realized in a Hofmann-type metal–organic framework with photochromic azobenzene guests.
Abstract
Stimuli-responsive materials that can be reversibly switched by light are of immense interest. Among them, photo-responsive spin crossover (SCO) complexes have great promises to combine the photoactive inputs with multifaceted outputs into switchable materials and devices. However, the reversible control the spin-state change by photochromic guests is still challenging. Herein, we report an unprecedented guest-driven light-induced spin change (GD-LISC) in a Hofmann-type metal–organic framework (MOF), [Fe(bpn){Ag(CN)2}2]⋅azobenzene. (1, bpn=1,4-bis(4-pyridyl)naphthalene). The reversible trans–cis photoisomerization of azobenzene guest upon UV/Vis irradiation in the solid-state results in the remarkable magnetic changes in a wide temperature range of 10–180 K. This finding not only establishes a new switching mechanism for SCO complexes, but also paves the way toward the development of new generation of photo-responsive magnetic materials.
Conflict of interest
The authors declare no conflict of interest.
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