Volume 60, Issue 39 p. 21074
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Inside Cover: Creation of High-Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster (Angew. Chem. Int. Ed. 39/2021)

Dr. Tokuhisa Kawawaki

Dr. Tokuhisa Kawawaki

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan

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Yuki Kataoka

Yuki Kataoka

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

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Momoko Hirata

Momoko Hirata

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

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Yuki Akinaga

Yuki Akinaga

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

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Dr. Ryo Takahata

Dr. Ryo Takahata

Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan

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Kosuke Wakamatsu

Kosuke Wakamatsu

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

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Yu Fujiki

Yu Fujiki

Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan

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Miori Kataoka

Miori Kataoka

Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan

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Dr. Soichi Kikkawa

Dr. Soichi Kikkawa

Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan

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Abdulrahman S. Alotabi

Abdulrahman S. Alotabi

Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia

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Dr. Sakiat Hossain

Dr. Sakiat Hossain

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

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Dr. D. J. Osborn

Dr. D. J. Osborn

Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia

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Prof. Toshiharu Teranishi

Prof. Toshiharu Teranishi

Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan

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Prof. Gunther G. Andersson

Prof. Gunther G. Andersson

Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia

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Prof. Gregory F. Metha

Prof. Gregory F. Metha

Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia

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Prof. Seiji Yamazoe

Prof. Seiji Yamazoe

Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan

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Prof. Yuichi Negishi

Corresponding Author

Prof. Yuichi Negishi

Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan

Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan

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First published: 12 July 2021
Citations: 1

Graphical Abstract

A ligand-desorption process during calcination was followed for metal-oxide-supported 2-phenylethanethiolate-protected gold 25-atom metal nanoclusters (NCs) using five experimental techniques by Yuichi Negishi and co-workers in their Research Article on page 21340. Based on the obtained knowledge, a method to form a metal-oxide layer on the surface of Au NCs while preventing their aggregation was established, and thereby a water-splitting photocatalyst with high activity and stability was created.

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