Inside Cover: Creation of High-Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster (Angew. Chem. Int. Ed. 39/2021)
Dr. Tokuhisa Kawawaki
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan
Search for more papers by this authorYuki Kataoka
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorMomoko Hirata
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorYuki Akinaga
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorDr. Ryo Takahata
Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan
Search for more papers by this authorKosuke Wakamatsu
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorYu Fujiki
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorMiori Kataoka
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorDr. Soichi Kikkawa
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorAbdulrahman S. Alotabi
Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia
Search for more papers by this authorDr. Sakiat Hossain
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorDr. D. J. Osborn
Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia
Search for more papers by this authorProf. Toshiharu Teranishi
Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan
Search for more papers by this authorProf. Gunther G. Andersson
Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia
Search for more papers by this authorProf. Gregory F. Metha
Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia
Search for more papers by this authorProf. Seiji Yamazoe
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorCorresponding Author
Prof. Yuichi Negishi
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan
Search for more papers by this authorDr. Tokuhisa Kawawaki
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan
Search for more papers by this authorYuki Kataoka
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorMomoko Hirata
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorYuki Akinaga
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorDr. Ryo Takahata
Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan
Search for more papers by this authorKosuke Wakamatsu
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorYu Fujiki
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorMiori Kataoka
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorDr. Soichi Kikkawa
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorAbdulrahman S. Alotabi
Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia
Search for more papers by this authorDr. Sakiat Hossain
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Search for more papers by this authorDr. D. J. Osborn
Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia
Search for more papers by this authorProf. Toshiharu Teranishi
Institute for Chemical Research, Kyoto University, Gokasho, Uji, 611-0011 Japan
Search for more papers by this authorProf. Gunther G. Andersson
Flinders Institute for Nanoscale Science and Technology, Flinders University, Adelaide, South Australia, 5042 Australia
Search for more papers by this authorProf. Gregory F. Metha
Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005 Australia
Search for more papers by this authorProf. Seiji Yamazoe
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo, 192-0397 Japan
Search for more papers by this authorCorresponding Author
Prof. Yuichi Negishi
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601 Japan
Photocatalysis International Research Center, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, 278-8510 Japan
Search for more papers by this authorGraphical Abstract
A ligand-desorption process during calcination was followed for metal-oxide-supported 2-phenylethanethiolate-protected gold 25-atom metal nanoclusters (NCs) using five experimental techniques by Yuichi Negishi and co-workers in their Research Article on page 21340. Based on the obtained knowledge, a method to form a metal-oxide layer on the surface of Au NCs while preventing their aggregation was established, and thereby a water-splitting photocatalyst with high activity and stability was created.