Volume 58, Issue 49 p. 17484
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Inside Cover: Structural Evolution of Water on ZnO(10urn:x-wiley:14337851:media:anie201913850:anie201913850-math-0001 0): From Isolated Monomers via Anisotropic H-Bonded 2D and 3D Structures to Isotropic Multilayers (Angew. Chem. Int. Ed. 49/2019)

Dr. Xiaojuan Yu

Dr. Xiaojuan Yu

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

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Dr. Paul Schwarz

Dr. Paul Schwarz

Interdisciplinary Center for Molecular Materials (ICMM) and Computer-Chemistry-Center (CCC), Friedrich-Alexander University Erlangen-Nürnberg (FAU), 91052 Erlangen, Germany

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Dr. Alexei Nefedov

Dr. Alexei Nefedov

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

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Prof. Dr. Bernd Meyer

Prof. Dr. Bernd Meyer

Interdisciplinary Center for Molecular Materials (ICMM) and Computer-Chemistry-Center (CCC), Friedrich-Alexander University Erlangen-Nürnberg (FAU), 91052 Erlangen, Germany

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Dr. Yuemin Wang

Corresponding Author

Dr. Yuemin Wang

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

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Prof. Dr. Christof Wöll

Corresponding Author

Prof. Dr. Christof Wöll

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

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First published: 08 November 2019

Graphical Abstract

An atomic-level picture of the structural evolution of water on the anisotropic ZnO(10urn:x-wiley:14337851:media:anie201913850:anie201913850-math-0002 0) surface was investigated by Y. Wang, C. Wöll et al. in their Research Article on page 17751 ff. by combining experiment and theory. IR spectroscopic evidence of isolated, intact D2O monomers is provided. The hydration proceeds further through an autocatalytic dissociation of dimers, followed by the formation of a mixed 2D D2O/OD adlayer and various complex H-bonded 3D structures.

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