Volume 58, Issue 44 p. 15937
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Inside Back Cover: Exploiting Coordination Isomerism for Controlled Self-Assembly (Angew. Chem. Int. Ed. 44/2019)

Nils Bäumer

Nils Bäumer

Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany

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Dr. Kalathil K. Kartha

Dr. Kalathil K. Kartha

Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany

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Dr. Naveen Kumar Allampally

Dr. Naveen Kumar Allampally

Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

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Prof. Dr. Shiki Yagai

Prof. Dr. Shiki Yagai

Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1–33-Yayoi-cho, Inage-Ku, Chiba, 263-8522 Japan

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Dr. Rodrigo Q. Albuquerque

Dr. Rodrigo Q. Albuquerque

Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany

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Prof. Dr. Gustavo Fernández

Corresponding Author

Prof. Dr. Gustavo Fernández

Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany

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First published: 11 October 2019

Graphical Abstract

Coordination isomerism can be used to control the morphology of a supramolecular polymer, as G. Fernández et al. show in their Communication on page 15626. Tuning the coordination isomerism of a PtII complex leads to tunable coordination isomerism, which in turn allows fully reversible switching between two distinct aggregate species (1D fibers↔2D lamellae) with different photoresponsive behavior. These observations pave the way for novel stimuli-responsive materials and offer a new approach for size control in self-assembled systems.

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